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Dependence of thermal expansion of LaNi0.6Fe0.4O3 − δ and La0.6Sr0.4Co0.2Fe0.8O3 − δ on oxygen partial pressure
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文摘

Thermal expansion coefficients, TEC, of cathode material for SOFC were measured.

TEC of LaNi0.6Fe0.4O3 − δ, LNF64, is independent on P(O2) and 1.27 × 10− 5 K− 1 at 500 °C.

La0.6Sr0.4Co0.2Fe0.8O3 − δ shows larger TEC which increases with decreasing P(O2).

LNF64 and 8YSZ shows high thermo-mechanical compatibility with close TEC.

Dependence of TEC on P(O2) is ascribed to the variation of oxygen nonstoichiometry.

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