Synthesis and structure characterization of bis- and mono(amidate) lanthanide (Ln = La, Gd) complexes and their application in the polymerization of ε-caprolactone
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- 作者：Yu-Long Wanga ; Yan-Xu Zhoua ; Le-Qing Denga ; Qing-Song Hua ; Xian Taob ; 18651656012@163.com" class="auth_mail" title="E-mail the corresponding author ; Ying-Zhong Shena ; yz_shen@nuaa.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Organolanthanide (La or Gd) ; Amidate ligands ; Polymerization of ε-caprolactone
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：805
- 期：Complete
- 页码：77-86
- 全文大小：1408 K
文摘
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Ten new amidate lanthanide complexes 1–10 (Ln = La or Gd) have been prepared.
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The single crystal structures of 2, 5, 6, 7, 8a, 9 and 10 were characterized by X-ray crystal structural analysis.
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The complexes 1, 2, 3, 5, 7, 9 and 10 were activity for the ring-opening polymerization of ε-caprolactone.