Tailoring dual redox-acid functionalities in VOx/TiO2/ZSM5 catalyst for simultaneous abatement of PCDD/Fs and NOx from municipal solid waste incineration
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- 作者：M. Gallastegi-Villa ; A. Aranzabal ; asier.aranzabal@ehu.es ; J.A. Gonzá ; lez-Marcos ; J.R. Gonzá ; lez-Velasco
- 关键词：MSW plants ; NOx ; PCDD/Fs ; Catalytic removal ; VOx/TiO2 ; VOx/zeolite ; Bifunctional catalyst
- 刊名：Applied Catalysis B: Environmental
- 出版年：2017
- 出版时间：15 May 2017
- 年：2017
- 卷：205
- 期：Complete
- 页码：310-318
- 全文大小：2413 K
- 卷排序：205
文摘
VOx/x%TiO2/ZSM5 catalysts were prepared tailoring redox and acid properties. TiO2 is heterogeneously dispersed over H-ZSM5 and VOx on the proximities of TiO2. Acid sites of the zeolite increase NO conversion widening temperature working window. Ti-V interactions lead to dispersed isolated and polymeric VOx species formation. V/46Ti/Z provides highest amount of Ti-V interactions and highest dDiNOx activity.