Synthesis, characteristics of hierarchical EU-1 zeolite for xylene isomerization probe reaction

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• 作者：Xiaofeng Li¹ ; ^{lixiaofeng6008@163.com} ; Pengchao Ren¹ ; Yanting Zhang¹ ; Xiaozhen Liu¹ ; Xiaotao Sun¹ ; Meng Gao¹ ; Miaojuan Jia¹ ; Zhiping Lü ; ¹ ; Tao Dou¹ ; ² ; ^{dtao1@163.com}
• 关键词：EU-1 ; Zeolite ; Hierarchical pore ; Synthesis ; Catalysis
• 刊名：Chinese Journal of Chemical Engineering
• 出版年：2016
• 出版时间：November 2016
• 年：2016
• 卷：24
• 期：11
• 页码：1577-1583
• 全文大小：1125 K
• 卷排序：24

文摘

Introduced a method of synthesizing hierarchical EU-1 zeolite with organosilanes as additive, and studied the influences of following different kinds of organosilanes on the synthesis of hierarchical EU-1 zeolite: γ-glycidoxy propyl trimethoxy silane (GPTMS), N-β-(aminoethyl)-γ-aminopropyl methyl dimethoxyl silane (APAEDMS), and N-(β-aminoethyl)-γ-aminopropyl dimethoxyl (ethyoxyl) silane (TMPED). The hierarchical EU-1 samples were characterized by XRD, SEM, N2 adsorption, FT-IR and NH3-TPD to analyze the crystallinity, morphology, surface area, pore size distribution and acidity. The results showed that hierarchical EU-1 zeolites were successfully synthesized; organosilanes have great influence on crystal morphology of EU-1 zeolites; the exterior surface area of hierarchical EU-1 zeolite, which synthesized with organosilanes (APAEDMS) adding into synthesis system, increased by 62.1% and mesopore volume increased by 129.1% compared with conventional EU-1 zeolites, thus can reduce the diffusional restriction markedly in catalytic reaction. The catalytic performance of hierarchical EU-1 zeolites were evaluated in m-xylene isomerization on fixed bed reactor. The catalytic data showed that the isomerization activity PX/X of the hierarchical EU-1 zeolites reached around 24.09% in theoretical thermodynamic equilibrium from 23.83%, and the selectivity of C8 aromatic hydrocarbon increased from 75.16% to 84.87%. The conversion of p-xylene increased from 16.30% to 18.41%.