Lignin-derived multi-cyclic high density biofuel by alkylation and hydrogenated intramolecular cyclization

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• 作者：Genkuo Nie ; Xiangwen Zhang ; Peijuan Han ; Junjian Xie ; Lun Pan ; Li Wang ; Ji-Jun Zou ; ^{jj_zou@tju.edu.cn}
• 关键词：Alkylation ; Hydrogenation ; Intramolecular cyclization ; Diphenylmethane ; Perhydrofluorene
• 刊名：Chemical Engineering Science
• 出版年：2017
• 出版时间：2 February 2017
• 年：2017
• 卷：158
• 期：Complete
• 页码：64-69
• 全文大小：1124 K
• 卷排序：158

文摘

High-density biofuel is synthesized from lignin-derived phenols. Biofuel has higher density and lower freezing point compared with literature. MMT-K10 selectively catalyzes alkylation of phenols with benzyl ether. Perhydrofluorene is formed by hydrogenated intramolecular cyclization.