Hydrodeoxygenation of methyl palmitate over MCM-41 supported nickel phosphide catalysts
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- 作者：Qingxin Guan ; Fanfan Wan ; Fei Han ; Zihe Liu ; Wei Li ; weili@nankai.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrodeoxygenation ; Methyl palmitate ; Nickel phosphide ; Phosphate ; Pentadecane
- 刊名：Catalysis Today
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：259
- 期：part_P2
- 页码：467-473
- 全文大小：1988 K
文摘
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Ni2P can be synthesized at 600 °C from its phosphate with a mole ratio of Ni/P = 2/1.
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Non-volatile cations can affect the generation of nickel phosphide.
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NixP for HDO of methyl palmitate was first tested in a fixed-bed microreactor.
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Reaction mechanism for HDO of methyl palmitate on NixP catalyst was proposed.