UTL titanosilicate: An extra-large pore epoxidation catalyst with tunable textural properties
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- 作者：Jan Přech ; jan.prech@jh-inst.cas.cz" class="auth_mail" title="E-mail the corresponding author ; Jiří ; Čejka
- 关键词：Titanosilicate UTL ; Top-down synthesis ; Epoxidation ; Catalysis ; Cyclooctene
- 刊名：Catalysis Today
- 出版年：2016
- 出版时间：15 November 2016
- 年：2016
- 卷：277
- 期：part_P1
- 页码：2-8
- 全文大小：1560 K
文摘
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UTL titanosilicate (Ti-UTL) was prepared.
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Ti-UTL was converted to related titanosilicates by ADOR process.
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Silica-titania pillaring concept was successfully applied producing Ti-IPC-1PITi.
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Ti-UTL showed activity similar to Ti-BEA in epoxidation of cyclooctene.
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Ti-IPC-1PITi is one of the most active catalysts for bulky substrates epoxidation.