Experimental measurement of solubility curves for poly(methyl methacrylate-co-pentafluorophenyl methacrylate) in supercritical solvents
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- 作者：Chang-Ryong Kim ; Hun-Soo Byun ; hsbyun@jnu.ac.kr" class="auth_mail" title="E-mail the corresponding author
- 关键词：Dispersion polymerization ; Supercritical CO2 ; P(MMA-co-PnFPMA) ; CH2F2 ; CHF3 ; CHClF2 ; High pressure phase behaviour ; Cloud-point curves
- 刊名：Journal of Chemical Thermodynamics
- 出版年：2016
- 出版时间：June 2016
- 年：2016
- 卷：97
- 期：Complete
- 页码：26-38
- 全文大小：2959 K
文摘
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The characterisation for the P(MMA-co-HFBMA) using the ratio of MMA vs HFBMA and AIBN content was investigated.
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Cloud-point data up to T = 454 K and 184 MPa are reported for the P(MMA-co-HFBMA) in CH2F2, CHF3 and CHClF2.
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Phase behaviour for the P(MMA-co-HFBMA) + CH2F2 + MMA mixtures are measured in changes from UCST to LCST behaviour.