Degradation kinetics of sodium alginate via sono-Fenton, photo-Fenton and sono-photo-Fenton methods in the presence of TiO₂ nanoparticles

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• 作者：Qingfeng Zhou ; Yanfeng Liu ; Gaobo Yu ; Furui He ; Kai Chen ; Dunchao Xiao ; Xinyu Zhao ; Yuhong Feng ; Jiacheng Li ; ^{ljcfyh@263.net} ; ^{lijiacheng@hainu.edu.cn}
• 关键词：Sodium alginate ; Degradation kinetics ; Fenton process ; sono-photo-Fenton ; TiO2 nanoparticles
• 刊名：Polymer Degradation and Stability
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：135
• 期：Complete
• 页码：111-120
• 全文大小：1666 K
• 卷排序：135

文摘

Sono-photo-Fenton, sono-Fenton and photo-Fenton methods combined with heterogeneous TiO2 nanoparticles are adopted to investigate the degradation of sodium alginate (NaAlg), and the kinetics mechanism is also explored. Experimental results suggest that the reaction order of NaAlg degradation (n) is 0.51 and the extent of photocatalytic degradation can increase with the loading of TiO2 nanoparticles. Meanwhile, as the catalyst concentration increases from 0.05 to 0.5 gL−1, the degradation rate constant (k) is decreased. In addition, the structure of degraded NaAlg is characterized by Fourier transform infrared (FT-IR), 1H NMR spectroscopy, and X-ray diffraction analyses. The FT-IR and 1H NMR spectra results indicate that the C2-C3 bond in the structure of NaAlg is broken and intra-molecular esters are formed during the degradation process due to the strong oxidization of the Fenton system. In general, the sono-photo-Fenton process with TiO2 nanoparticles could provide an efficient way to degrade the NaAlg to low-molecular-weight.