Photoinitiability of triblock copolymer PDMS-b-(PMAEBB-co-PDMAEMA)₂ as a macro-photoinitiator prepared via RAFT polymerization

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• 作者：Jiahui Su ; Xiaoxuan Liu ; Chengjing Xiong ; Hong Huang ; Yanyan Cui ; ^{anne800207@126.com}
• 关键词：Photopolymerization ; Macro-photoinitiator ; RAFT polymerization ; Polydimethylsiloxane ; Oxygen inhibition
• 刊名：Progress in Organic Coatings
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：103
• 期：Complete
• 页码：165-173
• 全文大小：2922 K
• 卷排序：103

文摘

A triblock copolymer is synthesized by RAFT polymerization as a novel macro-photoinitiator. The photoinitiation efficiency of macro-photoinitiator can be tuned by the RAFT polymerization process. The oxygen inhibition effect of photopolymerization is strongly suppressed by using the synthesized macro-photoinitiator.