Vibrationally high-resolved electronic spectra of MCl2 (M = C, Si, Ge, Sn, Pb) and photoelectron spectra of MCl2−
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- 作者：Yibin Ran ; Min Pang ; Wei Shen ; Ming Li ; Rongxing He ; herx@swu.edu.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Absorption and emission spectra ; Photoelectron spectra ; Anharmonic ; Franck&ndash ; Condon ; Herzberg&ndash ; Teller
- 刊名：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
- 出版年：2016
- 出版时间：5 October 2016
- 年：2016
- 卷：167
- 期：Complete
- 页码：1-11
- 全文大小：1979 K
文摘
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Spectra of group IV dichlorides and their anions were systematically investigated.
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Herzberg–Teller effect and anharmonic correction were taken into account.
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The simulated vibrational modes were confirmed and tentatively assigned.
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Resolved vibrational electronic spectrum of PbCl2 was reported for the first time.