Functionalized montmorillonite supported rhodium complexes: Efficient catalysts for carbonylation of methanol

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• 作者：Pallab Kumar Saikia ; Podma Pollov Sarmah ; Bibek Jyoti Borah ; Lakshi Saikia ; Dipak Kumar Dutta ; ^{dipakkrdutta@yahoo.com" class="auth_mail" title="E-mail the corresponding author} ; ^{dutta_dk@rrljorhat.res.in" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Anchoring ; Functionalization ; Rhodium ; Montmorillonite ; Carbonylation
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：412
• 期：Complete
• 页码：27-33
• 全文大小：1355 K

文摘

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d="par0005">Two new montmorillonite anchored Rh catalyst were synthesized and characterised.

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d="par0010">The catalysts were used in the carbonylation of methanol and recycled upto 3rd run.

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d="par0015">Conversion upto 99.9% was obtained without formation of methylacetate as byproduct.

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