Activation and selective oxy-functionalization of alkanes with metal complexes: Shilov reaction and some new aspects

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• 作者：Аlbert А. Shteinman ^{as237t@icp.ac.ru}
• 关键词：Metal complex catalysis ; Oxidation of alkanes ; Alkyl intermediates ; Alkane σ-complexes
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：305-315
• 全文大小：1466 K
• 卷排序：426

文摘

Shilov chemistry is paradigm of CH bond activation involving metal alkyls. The quest for new ideas in the field is actual now and is discussed in the review. New routes for activation and oxygenation of saturated hydrocarbons are discussed.