Thermally reversible self-healing polysilsesquioxane structure-property relationships based on Diels-Alder chemistry

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• 作者：Young Yeol Jo^a ; ^b ; Albert S. Lee^a ; Kyung-Youl Baek^a ; ^c ; Heon Lee^b ; Seung Sang Hwang^a ; ^c ; ^{sshwang@kist.re.kr}
• 关键词：Silsesquioxane ; Self-healing polymers ; Diels-Alder chemistry
• 刊名：Polymer
• 出版年：2017
• 出版时间：13 January 2017
• 年：2017
• 卷：108
• 期：Complete
• 页码：58-65
• 全文大小：1955 K
• 卷排序：108

文摘

A series of singular component self-healing polysilsesquioxanes were synthesized. Highly reversible Diels-Alder/retro-Diels-Alder chemistry enabled self-healing. Effect of chain mobility and interchain distance were examined.