Thermodynamics of (solute + solute) and (solute + solvent) interactions of homologous series of amino acids with thiamine hydrochloride in aqueous medium at T = (305.15, 310.15, 315.15) K: A volumetric and acoustic approach
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- 作者：Harsh Kumar ; h.786.man@gmail.com" class="auth_mail" title="E-mail the corresponding author ; manchandah@nitj.ac.in" class="auth_mail" title="E-mail the corresponding author ; Isha Behal
- 关键词：Amino acid ; Thiamine hydrochloride ; Density ; Speed of sound ; Apparent molar property ; Group contribution
- 刊名：Journal of Chemical Thermodynamics
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：102
- 期：Complete
- 页码：48-62
- 全文大小：728 K
文摘
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Densities and speeds of sound of amino acids in thiamine-HCl.
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Positive apparent molar volumes predict dominance of solute-solvent interactions.
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Positive transfer volumes indicate ion-ion interactions in the mixtures.
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Pair and triplet interaction coefficients predict pair wise interactions in mixtures.
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Amino acids act as structure maker in aqueous thiamine-HCl solutions.