A 4-fold interpenetrated diamondoid metal-organic framework with large channels exhibiting solvent sorption properties and high iodine capture
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- 作者：Gift Mehlana ; Gaë ; lle Ramon ; Susan A. Bourne ; susan.bourne@uct.ac.za" class="auth_mail" title="E-mail the corresponding author
- 关键词：Interpenetration ; Iodine capture ; Vapochromism ; Desolvation
- 刊名：Microporous and Mesoporous Materials
- 出版年：2016
- 出版时间：1 September 2016
- 年：2016
- 卷：231
- 期：Complete
- 页码：21-30
- 全文大小：2137 K
文摘
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The crystallinity of the activated material is maintained when the structure is partially loaded.
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Sorption of water above 10% by the activated phase triggers an irreversible structural transformation.
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Electron density of water molecules in the 3D network.
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As more water molecules gains access into the channels, an irreversible structural transformation occurs.