The BIAN ligand 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene: An electron sponge or a “normal” α-diimine ligand?

详细信息    查看全文

• 作者：Isabell Lö ; w^a ; Martina Bubrin^a ; Alexa Paretzki^a ; Jan Fiedler^b ; Stanislav Zá ; li&scaron ; ^b ; Wolfgang Kaim^a ; ^{kaim@iac.uni-stuttgart.de}
• 关键词：BIAN diimine ligand ; Carbonylmetal complexes ; Electron transfer ; Rhenium complexes ; Spectroelectrochemistry
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：540-548
• 全文大小：1359 K
• 卷排序：455

文摘

Combined (IR, UV–vis-NIR, EPR) spectroelectrochemical study of complexes [Re(CO)3Cl(L)] and [M(CO)5(L)], M = Cr,Mo,W. Reversible electrochemical oxidation of [Re(CO)3Cl(L)]. Mostly irreversible reduction despite two low lying orbitals of different character. No special electron reservoir behavior detected.