A₂B type copper(III)corroles containing zero-to-five fluorine atoms: Synthesis, electronic structure and facile modulation of electrocatalyzed hydrogen evolution

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• 作者：Minzhi Li^a ; ¹ ; Yingjie Niu^a ; ¹ ; Weihua Zhu^a ; ^{sayman@ujs.edu.cn} ; John Mack^b ; ^{j.mack@ru.ac.za} ; Gertrude Fomo^b ; Tebello Nyokong^b ; Xu Liang^a ; ^{liangxu@ujs.edu.cn}
• 关键词：Cu(III)corrole ; Electronic structure ; TD-DFT calculation ; Hydrogen evolution
• 刊名：Dyes and Pigments
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：137
• 期：Complete
• 页码：523-531
• 全文大小：2634 K
• 卷排序：137

文摘

A2B meso-substituted Cu(III)corroles have been synthesized and characterized. The electronic structure was analyzed by spectroscopy, electrochemistry, spectroelectrochemistry and TD-DFT calculations. These Cu(III)corroles can be used as highly effective catalysts for hydrogen evolution reactions (HERs). The modification to the structures of low symmetry corroles is a useful strategy for developing new HER catalysts.