Synthesis of Hetero-bifunctional, End-Capped Oligo-EDOT Derivatives

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• 作者：Christopher D. Spicer¹ ; Marsilea A. Booth¹ ; Damia Mawad¹ ; Astrid Armgarth¹ ; Christian B. Nielsen² ; Molly M. Stevens¹ ; ³ ; ^{m.stevens@imperial.ac.uk}
• 关键词：thiophene ; oligomer ; conjugated polymer ; C-H activation ; end capping ; synthesis
• 刊名：Chem
• 出版年：2017
• 出版时间：12 January 2017
• 年：2017
• 卷：2
• 期：1
• 页码：125-138
• 全文大小：2129 K
• 卷排序：2

文摘

A keto-acid end-capping strategy has been used to create stable oligo-EDOTs Oligomers can be synthesized in a facile manner via iterative direct arylation Hetero-bifunctional and mixed-monomer constructs can be controllably synthesized The keto-acid end group determines oligomer optical and electrochemical properties