Thermochemical properties of different 1-(R-phenyl)-1H-imidazoles

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• 作者：Vladimir N. Emel'yanenko^a ; ^b ; ^c ; Maria Kaliner^d ; Thomas Strassner^d ; ^{thomas.strassner@chemie.tu-dresden.de} ; Sergey P. Verevkin^a ; ^b ; ^{sergey.verevkin@uni-rostock.de}
• 关键词：1-(R-phenyl)-1H-imidazoles ; Vapor pressure ; Enthalpy of vaporization ; Enthalpy of formation ; Quantum-chemistry ; Structure-property relations
• 刊名：Fluid Phase Equilibria
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：433
• 期：Complete
• 页码：40-49
• 全文大小：872 K
• 卷排序：433

文摘

Methyl-, methoxy-, fluoro-, bromo-derivatives of phenyl-1H-imidazole synthesized. Vapor pressures measured by the transpiration method. Enthalpies of vaporization derived from pressure-temperature dependence. Consistency of vaporization enthalpies tested by a group contribution method. Gas-phase enthalpies of formation of phenyl-1H-imidazoles calculated by G3MP2.