Synergistic copper-TEMPO catalysis of intermolecular vicinal diamination of styrenes
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- 作者：Shiue-Shien Weng ; wengss@mail.cma.edu.tw ; Kun-Yi Hsieh ; Zih-Jian Zeng ; Jia-Wei Zhang
- 关键词：Intermolecular diamination of styrenes ; 2 ; 2 ; 6 ; 6-tetramethyl piperidine N-oxy radical ; N-fluorobenzenesulfonimide ; Radical addition ; Vicinal diamines
- 刊名：Tetrahedron Letters
- 出版年：2017
- 出版时间：15 February 2017
- 年：2017
- 卷：58
- 期：7
- 页码：670-673
- 全文大小：498 K
- 卷排序：58
文摘
Cu(I)-catalyzed intermolecular N-,N-bond installation across a double bond. N-fluorobenzenesulfonimide as the only nitrogen source. Reductive N-oxy radical and hexamethyldisilane benefit the catalytic turnover.