Structural comparison of copper(II) thiocyanate pyridine complexes

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• 作者：Joseph V. Handy ; Gerardo Ayala ; Robert D. Pike ; ^{rdpike@wm.edu}
• 关键词：Copper ; Thiocyanate ; Jahn-Teller ; Metal-organic network ; X-ray structure ; Polymorphism
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 February 2017
• 年：2017
• 卷：456
• 期：Complete
• 页码：64-75
• 全文大小：2027 K
• 卷排序：456

文摘

Copper(II) thiocyanate form trans square planar complexes with pyridines. Thiocyanate is always primarily N-bonded. Long Cu⋯S bonds span weakly bond monomers into chains or sheets. Pyridine substituent positions influence the degree of bonding.