Hydrogenation of 1-octene over skeletal Pd catalysts prepared from Pd-Zr amorphous alloys and the effect of Ni addition
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- 作者：Ai Nozakia ; Yasutomo Taniharaa ; Yasutaka Kuwaharaa ; b ; Tetsutaro Ohmichia ; Kohsuke Moria ; b ; Takeshi Nagasea ; c ; Hiroyuki Y. Yasudaa ; Hiromi Yamashitaa ; b ; yamashita@mat.eng.osaka-u.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Amorphous alloys ; Skeletal catalyst ; Hydrogenation
- 刊名：Catalysis Today
- 出版年：2016
- 出版时间：1 May 2016
- 年：2016
- 卷：265
- 期：Complete
- 页码：138-143
- 全文大小：1470 K
文摘
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Skeletal Pd was prepared from Pd–Zr amorphous alloy.
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The thermal treatment to precursors greatly affected to the catalytic activities of skeletal Pd.
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The effect of Ni addition on the catalytic properties was investigated.
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Skeletal PdNi showed superior selectivity in the hydrogenation of 1-octene.