On the advantages of spring magnets compared to pure FePt: Strategy for rare-earth free permanent magnets following a bottom-up approach

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• 作者：M. Pousthomis^a ; C. Garnero^a ; C.G. Marcelot^a ; ^b ; T. Blon^a ; S. Cayez^a ; C. Cassignol^c ; V.A. Du^c ; M. Krispin^c ; R. Arenal^d ; ^e ; ^f ; K. Soulantica^a ; G. Viau^a ; L.-M. Lacroix^a ; ^d ; ^{lmlacroi@insa-toulouse.fr" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Spring exchange ; Magnetic nanoparticles ; Recoil curves ; Binary assembly ; L10-FePt ; Soft phase
• 刊名：Journal of Magnetism and Magnetic Materials
• 出版年：2017
• 出版时间：15 February 2017
• 年：2017
• 卷：424
• 期：Complete
• 页码：304-313
• 全文大小：1747 K

文摘

Nanostructured magnets benefiting from efficient exchange-coupling between hard and soft grains represent an appealing approach for integrated miniaturized magnetic power sources. Using a bottom-up approach, nanostructured materials were prepared from binary assemblies of bcc FeCo and fcc FePt nanoparticles and compared with pure L1₀-FePt materials. The use of a bifunctional mercapto benzoic acid yields homogeneous assemblies of the two types of particles while reducing the organic matter amount. The 650 °C thermal annealing, mandatory to allow the L1₀-FePt phase transition, led to an important interdiffusion and thus decreased drastically the amount of soft phase present in the final composites. The analysis of recoil curves however evidenced the presence of an efficient interphase exchange coupling, which allows obtaining better magnetic performances than pure L1₀ FePt materials, energy product above 100 kJ m⁻³ being estimated for a Pt content of only 33%. These results clearly evidenced the interest of chemically grown nanoparticles for the preparation of performant spring-magnets, opening promising perspective for integrated subcentimetric magnets with optimized properties.