The reduction of 4-chloronitrobenzene by Fe(II)-Fe(III) oxide systems - correlations with reduction potential and inhibition by silicate
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- 作者：Adele M. Jones ; adele.jones1@unsw.edu.au" class="auth_mail" title="E-mail the corresponding author ; Andrew S. Kinsela ; Richard N. Collins ; T. David Waite ; d.waite@unsw.edu.au" class="auth_mail" title="E-mail the corresponding author
- 关键词：Reduction kinetics ; Mediated electrochemistry ; Redox potential ; Contaminant degradation
- 刊名：Journal of Hazardous Materials
- 出版年：2016
- 出版时间：15 December 2016
- 年：2016
- 卷：320
- 期：Complete
- 页码：143-149
- 全文大小：1044 K
文摘
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The impact of silica on Fe(II)-Fe(III) oxide reduction potentials is unknown.
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Reduction potentials determined using mediated open circuit potentiometry.
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Reduction kinetics and measured reduction potentials generally well correlated.
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Kinetics slower than predicted from reduction potential for Si-doped ferrihydrite.
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Contaminant degradation in high silicate groundwaters may be less effective.