Preparation and infrared to visible upconversion luminescence of Yb₂O₃:Ho³⁺ nanocrystalline powders

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• 作者：Weihua Guo^a ; ^b ; Hongshun Hao^a ; ^b ; ^{beike1952@163.com} ; Shanshan Jin^a ; ^b ; Qing Su^a ; ^b ; Hong Li^a ; ^b ; Xiaofei Hu^a ; ^b ; YiJie Gan^a ; ^b ; Lei Qin^c ; Wenyuan Gao^a ; ^b ; Guishan Liu^a ; ^b
• 关键词：Powders ; Solid state reaction ; X-ray methods ; Optical properties
• 刊名：Ceramics International
• 出版年：2017
• 出版时间：1 April 2017
• 年：2017
• 卷：43
• 期：5
• 页码：4330-4334
• 全文大小：965 K
• 卷排序：43

文摘

Yb2O3:Ho3+ nanocrystalline powders were synthesized through a solid state reaction method. X-ray diffraction analysis and field emission scanning electron microscopy were used to analyze the phase composition and morphology of the powders. Then under the 980 nm excitation of laser diode, the fluorescence of the crystals was studied via a fluorescence spectrometer. The green and red emissions centered on 551 and 668 nm were observed, and the green band dominated the emission spectrum. The effect of the concentration of Ho3+ on the upconversion luminescence intensity was discussed and the possible upconversion emission mechanism was explained. It indicates that like other metal oxide nanoparticles, Yb2O3 could also be a potential host material for doping to prepare the upconversion phosphor.