Synthesis, crystal structures and coordination modes of some triorganotin(IV) complexes with 2-N-propyl and 2-N-benzyl-amino-1-cyclopentene-1-dithiocarboxylates
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- 作者：Marcela Ló ; pez-Cardosoa ; Gabriela Vargas-Pinedaa ; Perla Patricia Romá ; n-Bravoa ; Cristina Rodrí ; guez-Narvá ; eza ; Elena Rosas-Valdeza ; Raymundo Cea-Olivaresb ; cea@unam.mx" class="auth_mail" title="E-mail the corresponding author
- 关键词：Triorganotin(IV) ; Carbodithioates ; Coordination modes ; Organotin complexes
- 刊名：Journal of Molecular Structure
- 出版年：2016
- 出版时间：15 July 2016
- 年：2016
- 卷：1116
- 期：Complete
- 页码：116-121
- 全文大小：612 K
文摘
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Six new triorganotin (IV) complexes with N-substituted ACDA ligands are reported.
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In the complexes only the carbodihioate group is coordinated to tin(IV).
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Tin(IV) atoms are coordinated in an anisobidentate fashion.
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The coordination geometry of the tin atoms is distorted Ψ-trigonal-bipyramidal.