Sensing of insulin fibrillation using alkoxy-bridged binuclear rhenium(I) complexes
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- 作者：Veerasamy Sathisha ; Arumugam Ramdassb ; Zong-Zhan Luc ; Murugesan Velayudhamc ; d ; Pounraj Thanasekaranc ; ptsekaran@yahoo.com" class="auth_mail" title="E-mail the corresponding author ; Kuang-Lieh Luc ; kllu@gate.sinica.edu.tw" class="auth_mail" title="E-mail the corresponding author ; Seenivasan Rajagopale ; rajagopalseenivasan@yahoo.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Re(I) complexes ; Luminescence enhancement ; Insulin fibrils ; Hydrophobic ; π ; &minus ; ; π stacking interaction
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：73
- 期：Complete
- 页码：49-51
- 全文大小：800 K
文摘
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Insulin fibrils enhances the luminescence of binuclear Re(I) complexes.
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A sensitive and selective method for the determination of insulin fibrils was developed.
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The strong binding of insulin with Re(I) complexes are attributed to hydrophobic as well as π-π stacking interactions.