Hydrogenolysis/hydrogenation of diphenyl ether as a model decomposition reaction of lignin from biomass in pressurized CO₂/water condition

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• 作者：Maya Chatterjee^a ; ^{c-maya@aist.go.jp} ; Takayuki Ishizaka^a ; ^{t-ishizaka@aist.go.jp} ; Hajime Kawanami^a ; ^b ; ^{h-kawanami@aist.go.jp}
• 关键词：Heterogeneous catalyst ; CO bond cleavage ; Pressurized CO2/water ; Hydrogen pressure
• 刊名：Catalysis Today
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：281
• 期：part_P2
• 页码：402-409
• 全文大小：958 K
• 卷排序：281

文摘

A significant role of hydrogen pressure was proposed on catalytic performances. Critically controlled hydrogen pressure confirmed the effective CO bond cleavage. High temperature and organic solvent hampered the turnover frequency (TOF CO).