Fe-Beta zeolite for selective catalytic reduction of NO_x with NH₃: Influence of Fe content

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• 作者：Yan Xia ; Wangcheng Zhan ; ^{zhanwc@ecust.edu.cn} ; Yun Guo ; Yanglong Guo ; Guanzhong Lu ; ^{gzhlu@ecust.edu.cn}
• 关键词：Beta zeolite ; Selective catalytic reduction ; Fe content ; Fe species ; Ion exchange
• 刊名：Chinese Journal of Catalysis
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：37
• 期：12
• 页码：2069-2078
• 全文大小：843 K
• 卷排序：37

文摘

Fe doped Beta zeolite with different Fe contents were prepared by ion exchange by changing the volume or the concentration of a Fe salt solution. For a particular mass of Fe salt precursor, the concentration of the metal salt solution during ion exchange influenced the ion exchange capacity of Fe, and resulted in different activities of the Fe-Beta catalyst. Fe-Beta catalysts with the Fe contents of (2.6, 6.3 and 9) wt% were synthesized using different amounts of 0.02 mol/L Fe salt solution. These catalysts were studied by various characterization techniques and their NH3-SCR activities were evaluated. The Fe-Beta catalyst with the Fe content of 6.3 wt% exhibited the highest activity, with a temperature range of 202–616 °C where the NOx conversion was > 80%. The Fe content in Beta zeolite did not influence the structure of Beta zeolite and valence state of Fe. Compared with the Fe-Beta catalysts with low Fe content (2.6 wt%), Fe-Beta catalysts with 6.3 wt% Fe content possessed more isolated Fe3+ active sites which led to its higher NH3-SCR activity. A high capacity for NH3 and NO adsorption, and a high activity for NO oxidation also contributed to the high NH3-SCR activity of the Fe-Beta catalyst with 6.3 wt%. However, when the Fe content was further increased to 9.0 wt%, the amount of FexOy nanoparticles increased while the amount of isolated Fe3+ active sites was unchanged, which promoted NH3 oxidation and decreased the NH3-SCR activity at high temperature.