Di- and tri-nuclear ruthenium nitrosyl complexes containing thiolate ligands

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• 作者：Ka-Wang Chan ; Wai-Ming Ng ; Wai-Man Cheung ; ^{cheungwm@ust.hk" class="auth_mail" title="E-mail the corresponding author} ; Chun-Sing Lai ; Herman H.Y. Sung ; Ian D. Williams ; Wa-Hung Leung ; ^{chleung@ust.hk" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Ruthenium ; Nitrosyl ; Thiolate ; Cluster
• 刊名：Journal of Organometallic Chemistry
• 出版年：2016
• 出版时间：15 June 2016
• 年：2016
• 卷：812
• 期：Complete
• 页码：151-157
• 全文大小：965 K

文摘

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d="p0010">Ruthenium thiolate nitrosyl complexes have been synthesized and structurally characterized.

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d="p0015">The outcome of the reaction of Ru(NO)Cl₃ with NaSR is dependent on the nature of the thiolate ligand.

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d="p0020">C&ndash;S cleavage of the tert-butylthiolate ligand results in the formation of a trinuclear ruthenium sulfido cluster.

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