A novel hexanuclear silver(I) complex with photoluminescence properties

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• 作者：Yining Wu^a ; Xuepeng Wu^a ; ^{wuxuepeng@163.com} ; Sisi Fang^a ; Shuai Yang^a ; Weitao Li^a ; Huan Wang^c ; Xiaoxi Yu^b ; ^{yuxiaoxi0217@live.cn}
• 关键词：Silver complex ; Crystal structure ; Ag&ndash ; Ag interaction ; DFT calculation ; Photoluminescence
• 刊名：Polyhedron
• 出版年：2017
• 出版时间：28 January 2017
• 年：2017
• 卷：122
• 期：Complete
• 页码：155-160
• 全文大小：1872 K
• 卷排序：122

文摘

A hexanuclear complex of d10–d10 transition metal with organosulfur ligand, Ag6(py2t)6 (py2t = pyrazine-2-thiol), has been synthesized using diffusion methodology at room temperature. Crystal structure was revealed using single crystal X-ray diffraction and data indicate that the complex synthesized containing Ag–Ag bonds in the silver cluster. The density function theory (DFT) calculation was performed to investigate the molecular orbital and photoluminescence potential. The photoluminescence properties of the complex have been further investigated, and a favorable fluorescence property was observed from the complex.