Halide ions pose special promotion in the photolysis of sulfamethazine.
Photolytic rate of sulfamethazine is higher in seawater than that in freshwater.
Triplet-excited sulfamethazine can react with Cl− and Br− ions.
Halogenated intermediates of sulfamethazine were formed in seawater.
Halogenation reaction can be predicted based on oxidation potential.
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