Facet-coupling NaTaO3/Ta2O5 was obtained by a synchronous etching-growth approach.
The matched etching kinetics of Ta2O5 with the growth rate of NaTaO3 is pivotal.
Facet-coupling NaTaO3/Ta2O5 shows improved light absorption and charge separation.
It exhibits an excellent photocatalytic activity in the absence of any cocatalysts.
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