Hydrothermal crystal growth and Vernier structures of the metal benzenedicarboxylates MIL-47 and MIL-53 containing guest molecules of benzenecarboxylic acid
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- 作者：Xiqu Wang ; Allan J. Jacobson ; ajjacob@uh.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Hydrothermal synthesis ; Vernier crystal structures ; Metal benzene dicarboxylates ; MIL-47 ; MIL-53
- 刊名：Journal of Solid State Chemistry
- 出版年：2016
- 出版时间：April 2016
- 年：2016
- 卷：236
- 期：Complete
- 页码：230-235
- 全文大小：1255 K
文摘
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Crystal growth of MIL-47, MIL-53Al, and MIL-53Ga.
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The Vernier structures have corner-sharing MO6 octrahedral chains and chains of H2BDC molecules.
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The stoichiometry is determined by the ratio of the host framework to the guest H2BDC column lengths.
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A correlation is established between the stoichiometry and the radius of the metal ion.
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All atoms in the Al and Ga compounds show sinusoidal modulations transverse to the channel axis.