Ultraviolet radiation-induced accelerated degradation of chitosan by ozone treatment

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• 作者：Wu Yue ; Rian He ; Pingjia Yao ; Yuanan Wei
• 关键词：Degradation ; Chitosan ; Ultraviolet radiation ; Ozone
• 刊名：Carbohydrate Polymers
• 出版年：2009
• 出版时间：11 July 2009
• 年：2009
• 卷：77
• 期：3
• 页码：639-642
• 全文大小：380 K

文摘

Combined with ultraviolet radiation as an accessory factor, ozone can result in accelerated degradation of chitosan. The ultraviolet radiation-induced accelerated degradation of chitosan was demonstrated by means of determination of viscosity-average molecular weight (Mv). In addition, the structure of the degraded chitosan obtained by ozone treatment combined with ultraviolet radiation was characterized by FT-IR, ¹³C NMR, and X-ray diffraction spectral analysis. The chemical structure of the degraded chitosan sample was not obviously modified. There was no significant change of the total degree of deacetylation (DD) of degraded chitosan compared with the initial chitosan. The technique of the combination of ozone and ultraviolet radiation is promisingly suitable for scale-up industrial manufacture of low-molecular-weight chitosan.