Polar and low polar solvents media effect on dipole moments of some diazo Sudan dyes
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- 作者：M.S. Zakerhamidi<sup>asup><sup> ; sup><sup>Zakerhamidi@tabrizu.ac.ir" class="auth_mailsup> ; Sh. Golghasemi Sorkhabi<sup>asup> ; A.N. Shamkhali<sup>bsup><sup> ; sup><sup>csup>
- 关键词：Dipole moment ; Diazo Sudan dye ; Solvent&ndash ; solute interaction ; Solvent polarity ; Tautomeric resonance structure ; Intramolecular charge-transfer
- 刊名：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
- 出版年：5 June, 2014
- 年：2014
- 卷：127
- 期：Complete
- 页码：340-348
- 全文大小：1565 K
文摘
Absorption and fluorescence spectra of three Sudan dyes (Sudan<sub>IIIsub>, Sudan<sub>IVsub> and Sudan black B) were recorded in various solvents with different polarity in the range of 300-800 nm, at room temperature. The solvatochromic method was used to investigate dipole moments of these dyes in ground and excited states, in different media. The solvatochromic behavior of these substances and their solvent-solute interactions were analyzed via solvent polarity parameters. Obtained results express the effects of solvation on tautomerism and molecular configuration (geometry) of Sudan dyes in solvent media with different polarity. Furthermore, analyze of solvent-solute interactions and value of ground and excited states dipole moments suggests different forms of resonance structures for Sudan dyes in polar and low-polar solvents.