Keggin polyoxometalate with pendant tricyclic, aromatic entity

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• 作者：Han ; Zhangang ; Zhao ; Yulong ; Peng ; Jun ; Ma ; Huiyuan ; Liu ; Qun ; Wang ; Enbo
• 关键词：Polyoxometalate ; Lacunary tungstophosphate ; Organic capped-structure ; 5-phenyl-2-(4-pyridinyl)pyridine ; Cobalt
• 刊名：Journal of Molecular Structure
• 出版年：2005
• 出版时间：March 14, 2005
• 年：2005
• 卷：738
• 期：1-3
• 页码：1-7
• 全文大小：313 K

文摘

A Keggin polyoxometalate with pendant tricyclic, aromatic entity, formulated as (Hpbpy)₅[PW₁₁O₃₉Co(pbpy)]·2H₂O (1) (pbpy=5-phenyl-2-(4-pyridinyl)pyridine), was synthesized and characterized by X-ray single crystal structure analysis and temperature-dependent magnetic susceptibility, which represents an unprecedented organic capped-structure. Crystal data: C₉₆H₈₁N₁₂O₄₁PCoW₁₁, triclinic, P−1, a