Transition metal-free catalytic oxidation of aromatic alcohols with molecular oxygen in the presence of a catalytic amount of N-bromosuccinimide
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- 作者：Xinli Tonga ; tongxinli@tju.edu.cn" class="auth_mail ; tongxli@sohu.com" class="auth_mail ; Yongfa Suna ; Yongtao Yana ; Xuan Luob ; Jinbiao Liua ; Zhidong Wua
- 关键词：Oxidation ; Aromatic alcohols ; Oxygen ; Transition metal-free ; N-Bromosuccinimide
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：September 2014
- 年：2014
- 卷：391
- 期：Complete
- 页码：1-6
- 全文大小：1076 K
文摘
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A new transition metal-free catalyst system for aerobic oxidation is developed.
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The efficient oxidation of alcohols with molecular oxygen is achieved.
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The catalytic system is composed of DDQ, NaNO2 and NBS.
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76–99% yields of aldehydes are obtained from oxidation of aromatic alcohols.