Synthesis and structures of two luminescent Zn(II) complexes with pyrazole and carboxylate ligands

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• 作者：Li ; Jing ; Zhou ; Jian-Hao ; Li ; Yi-Zhi ; Weng ; Lin-Hong ; Chen ; Xue-Tai ; Yu ; Zhi ; Xue ; Ziling
• 关键词：Zinc ; Pyrazole ; Betaine ; Crystal structure ; Luminescence
• 刊名：Inorganic Chemistry Communications
• 出版年：2004
• 出版时间：April, 2004
• 年：2004
• 卷：7
• 期：4
• 页码：538-541
• 全文大小：193 K

文摘

Two new Zn(II) complexes with pyrazole and carboxylate ligands, [Zn(μ-pz)(pzH)(O₂CCH₂CH₃)]₂ (pzH = pyrazole), 1 and [Zn(bet)₂(pzH)₂](ClO₄)₂ (bet = Me₃NCH₂CO₂), 2, were prepared and structurally characterized. Both compounds exhibit blue emission at room temperature in solid state.