Bimetallic Ru:Ni/MCM-48 catalysts for the effective hydrogenation of d-glucose into sorbitol

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• 作者：Alberto Romero^a ; Antonio Nieto-Má ; rquez^b ; Esther Alonso^a ; ^{ealonso@iq.uva.es}
• 关键词：Hydrogenation of sugars ; Sorbitol ; Ruthenium-nickel bimetallic catalysts ; MCM-48 ; d-Glucose
• 刊名：Applied Catalysis A: General
• 出版年：2017
• 出版时间：5 January 2017
• 年：2017
• 卷：529
• 期：Complete
• 页码：49-59
• 全文大小：4109 K
• 卷排序：529

文摘

Notable influence of the addition of different amounts of Ru to Ni/MCM-48. Ru:Ni ratios higher than 0.45 improved the catalytic behavior of Ni/MCM-48. Good stability of Ru:Ni/MCM-48 (0.45) was observed after three reaction cycles. Ru:Ni/MCM-48 enhanced selectivity of sorbitol in comparison with Ni/MCM-48.