Optical properties of a binuclear neodymium complex in phosphorus oxychloride for liquid laser
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- 作者：Guofang Zhanga ; Jiangbo Sheb ; shejb@opt.ac.cn" class="auth_mail" title="E-mail the corresponding author ; Kai Hana ; Rongzhi Nieb ; Dongdong Lic ; Bo Pengb ; bpeng@opt.ac.cn" class="auth_mail" title="E-mail the corresponding author
- 关键词：Crystal structure ; Optical property ; Judd&ndash ; Ofelt theory ; Liquid laser ; Emission cross-section
- 刊名：Optical Materials
- 出版年：2015
- 出版时间：November 2015
- 年：2015
- 卷：49
- 期：Complete
- 页码：343-347
- 全文大小：630 K
文摘
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First, the binuclear Nd(CF3COO)3·(Ph3PO)2 (Ph3PO: triphenylphosphine oxide) single-crystal was grown and its molecular structure presented.
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Second, based on Judd–Ofelt theory and crystal structure, the effects of luminescent centers’ crystal field and bond valance properties on materials’ optical properties were analyzed in detail.
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Third, the emission cross-section of 4F3/2 → 4I11/2 fluorescence transition of the complex was 2.78 × 10−20 cm2.