Levels and distribution of Dechlorane Plus in coastal sediments of the Yellow Sea, North China

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• 作者：Zhen Zhao^a ; ^b ; ^c ; ^d ; Guangcai Zhong^a ; ^b ; ^d ; Axel Mö ; ller^b ; Zhiyong Xie^b ; ^{zhiyong.xie@hzg.de} ; Renate Sturm^b ; Ralf Ebinghaus^b ; Jianhui Tang^a ; Gan Zhang^c
• 关键词：Dechlorane Plus ; Coastal sediment ; North China ; Alternative flame retardant
• 刊名：Chemosphere
• 出版年：2011
• 出版时间：May 2011
• 年：2011
• 卷：83
• 期：7
• 页码：984-990
• 全文大小：761 K

文摘

Dechlorane Plus (DP) has been determined in surface sediments from three Chinese coastal bays, e.g. Jiaozhou, Sishili and Taozi Bay in North China. DP concentrations ranged from <1.2 to 187 pg g⁻¹ dry weight (dw) (mean: 24.7 pg g⁻¹ dw) in Jiaozhou Bay, <1.2 to 135 pg g⁻¹ dw (mean 69.9 pg g⁻¹ dw) in Sishili Bay and <1.2 to 66.7 pg g⁻¹ dw (mean: 40.4 pg g⁻¹ dw) in Taozi Bay, respectively. Additionally, two dechlorinated species were quantified, which accounted for 0.6–5.1 % of the ∑DP concentration.

The f_syn values (syn-isomer/(syn- + anti-isomer)) in sediments from Jiaozhou Bay (mean 0.29) were close to the technical DP mixture (0.2–0.4), probably indicating local inputs of DP. In contrast, sediments in Sishili and Taozi Bay showed much lower f_syn values (mean 0.16). During transportation the DP isomers are subject to stereo selective degradation which partly resulted in the relative enrichment of anti-DP in coastal sediments.