In-situ nitration and syntheses of new Co(II) and Ni(II) complexes assembled from 3-methyl-1-phenyl-5-pyrazolone and cobalt or nickel nitrate under solvothermal conditions

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• 作者：Ruibo Xu ; Mingxiu Liang ; Fujun Yin ; Shuan Li ; Yuping Huang ; Yuxia Zhaoa ; Jiao Liu ; Weixing Ma
• 关键词：Nitration ; In-situ synthesis ; Solvothermal reaction ; 3-methyl-1-phenyl-5-pyrazolone ; Cobalt/nickel nitrate
• 刊名：Inorganic Chemistry Communications
• 出版年：February, 2014
• 年：2014
• 卷：40
• 期：Complete
• 页码：120-123
• 全文大小：613 K

文摘

Two new mononuclear complexes, [Co(L^{鈭?/sup>)₂(H₂O)₂] (1) and [Ni(L鈭?/sup>)₂(H₂O)₂] (2) (HL = 3-methyl-4-nitro-1-phenyl-5-pyrazolone), have been synthesized by the solvothermal reaction of Co(NO₃)₂ or Ni(NO₃)₂ with MPP (MPP = 3-methyl-1-phenyl-5-pyrazolone) in acetonitrile solution, and the ligand HL was generated in-situ through the nitration of MPP mediated by cobalt or nickel nitrate rather than mixture acids. Single crystal X-ray diffraction of 1 reveals that 1 consists of one Co(II), two L鈭?/sup> and two coordinated water molecules, and Co(II) adopts slightly octahedral geometry. Through intermolecular hydrogen bonding interactions, 1 presents two-dimensional network. Furthermore, the plausible nitration mechanism of MPP was also discussed.}