Triple Bonds between Transition Metals and the Heavier Elements of Groups 14 and 15
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- 作者：Gá ; bor Balá ; zs ; Laurence J. Gregoriades ; Manfred Scheer
- 刊名：Organometallics
- 出版年：2007
- 出版时间：June 18, 2007
- 年：2007
- 卷：26
- 期：13
- 页码：3058 - 3075
- 全文大小：399K
- 年卷期：v.26,no.13(June 18, 2007)
- ISSN：1520-6041
文摘
In the mid-1990s, the first examples of complexes containing triple bonds between transition metalsand heavier analogues of the carbon as well as the nitrogen groups were reported, thus signaling thebeginning of a new era in organometallic chemistry. Since then the progress in this field has beentremendous, with a large number of representative complexes being isolated and characterized. Thisreview highlights the astonishing development of the chemistry of complexes containing triple bondsbetween transition metals and the heavier elements of groups 14 and 15 since its birth. The synthesis andthe structural and spectroscopic features of these compounds are comprehensively discussed. Furthermore,the elucidation of their bonding modes by quantum-chemical methods as well as the relation betweenthe reactivities of these complexes and their electronic structures are presented.