Photo-cross-linked Poly(thioether-co-carbonate) Networks Derived from the Natural Product Quinic Acid
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- 作者：Lauren A. Link ; Alexander T. Lonnecker ; Keith Hearon ; Cameron A. Maher ; Jeffery E. Raymond ; Karen L. Wooley
- 刊名：ACS Applied Materials & Interfaces
- 出版年：2014
- 出版时间：October 22, 2014
- 年：2014
- 卷：6
- 期：20
- 页码：17370-17375
- 全文大小：292K
- ISSN：1944-8252
文摘
Polycarbonate networks derived from the natural product quinic acid that can potentially return to their natural building blocks upon hydrolytic degradation are described herein. Solvent-free thiol鈥揺ne chemistry was utilized in the copolymerization of tris(alloc)quinic acid and a variety of multifunctional thiol monomers to obtain poly(thioether-co-carbonate) networks with a wide range of achievable thermomechanical properties including glass transition temperatures from 鈭?8 to +65 掳C and rubbery moduli from 3.8 to 20 MPa. The network containing 1,2-ethanedithiol expressed an average toughness at 25 and 63 掳C of 1.08 and 2.35 MJ/m3, respectively, and an order-of-magnitude increase in the average toughness at 37 掳C of 15.56 MJ/m3.