Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands

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• 作者：Andrew Brown ; Mohamed Saber ; Willem Van den HeuvelKelsey Schulte ; Alessandro Soncini ; Kim R. Dunbar
• 刊名：Inorganic Chemistry
• 出版年：2017
• 出版时间：February 6, 2017
• 年：2017
• 卷：56
• 期：3
• 页码：1031-1035
• 全文大小：292K
• ISSN：1520-510X

文摘

The titanium(III) cyanide compound [Et₄N][Tp*Ti(CN)₃] ([Et₄N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = ¹/₂ paramagnet and that it exhibits significant temperature-independent paramagnetism.