Selective Lateral Lithiation of Methyl BODIPYs: Synthesis, Photophysics, and Electrochemistry of New Meso Derivatives
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- 作者：Eduardo Palao ; Santiago de la Moya ; Antonia R. Agarrabeitia ; Ixone Esnal ; Jorge Ba帽uelos ; 脥帽igo L贸pez-Arbeloa ; Mar铆a J. Ortiz
- 刊名：Organic Letters
- 出版年：2014
- 出版时间：September 5, 2014
- 年：2014
- 卷：16
- 期：17
- 页码：4364-4367
- 全文大小：320K
- ISSN：1523-7052
文摘
Selected meso BODIPYs (chemically reactive, difficult to obtain by established procedures, or photophysically or electrochemically attractive) have been obtained by unprecedented selective lateral lithiation of 8-methylBODIPYs. The physical study of the obtained new meso BODIPYs reveals interesting tunable properties related to the activation of intramolecular charge-transfer processes, endorsing the new synthetic methodology as useful for the development of smarter BODIPY dyes for technological applications.