A Crystalline Porous Coordination Polymer Decorated with Nitroxyl Radicals Catalyzes Aerobic Oxidation of Alcohols
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- 作者：Liangchun Li ; Ryotaro Matsuda ; Iku Tanaka ; Hiroshi Sato ; Prakash Kanoo ; Hyung Joon Jeon ; Maw Lin Foo ; Atsushi Wakamiya ; Yasujiro Murata ; Susumu Kitagawa
- 刊名：Journal of the American Chemical Society
- 出版年：2014
- 出版时间：May 28, 2014
- 年：2014
- 卷：136
- 期：21
- 页码：7543-7546
- 全文大小：339K
- 年卷期：v.136,no.21(May 28, 2014)
- ISSN：1520-5126
文摘
A porous coordination polymer (PCP) has been synthesized employing an organic ligand in which a stable free radical, isoindoline nitroxide, is incorporated. The crystalline PCP possesses one-dimensional channels decorated with the nitroxyl catalytic sites. When O2 gas or air was used as the oxidant, this PCP was verified to be an efficient, recyclable, and widely applicable catalyst for selective oxidation of various alcohols to the corresponding aldehydes or ketones.