Palladium-Catalyzed Carbonation鈥揇iketonization of Terminal Aromatic Alkenes via Carbon鈥揘itrogen Bond Cleavage for the Synthesis of 1,2-Diketones

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• 作者：Azhong Wang ; Huanfeng Jiang ; Xianwei Li
• 刊名：Journal of Organic Chemistry
• 出版年：2011
• 出版时间：August 19, 2011
• 年：2011
• 卷：76
• 期：16
• 页码：6958-6961
• 全文大小：773K
• 年卷期：v.76,no.16(August 19, 2011)
• ISSN：1520-6904

文摘

A palladium-catalyzed carbonation鈥揹iketonization reaction of terminal alkenes via carbon鈥搉itrogen bond cleavage under an atmosphere of oxygen has been developed. A series of 1,2-diketones were readily prepared from the reaction of aromatic terminal alkenes with nitroalkanes.